Volatile Metals Coordination Compounds as Precursors for Functional Materials Synthesis by CVD-Method
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چکیده
منابع مشابه
Volatile magnesium octahydrotriborate complexes as potential CVD precursors to MgB2. Synthesis and characterization of Mg(B3H8)2 and its etherates.
The solid-state reaction of MgBr2 and NaB3H8 at 20 degrees C, followed by sublimation at 80 degrees C and 0.05 Torr, affords Mg(B3H8)2 as a white solid. Similar reactions with MgBr2(Et2O) and MgBr2(Me2O)1.5 afford the crystalline ether adducts Mg(B3H8)2(Et2O)2 and Mg(B3H8)2(Me2O)2, respectively. In contrast, reactions of MgBr2 with NaB3H8, the presence of excess solvent result in the formation ...
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ژورنال
عنوان ژورنال: Le Journal de Physique IV
سال: 1995
ISSN: 1155-4339
DOI: 10.1051/jphyscol:1995564